个人简介
夏远志,博士,教授,博士生导师。曾任beat365官方网站副院长,现任教务处副处长,绿色合成与药物化学研究所所长,化学国家一流专业负责人,化学一级学科硕士点负责人,韩国全南大学博士生导师,浙江省高等学校化学类与化工制药类专业教学指导委员会委员。
2004年本科毕业于湖北大学化学专业,2009年博士毕业于中国科学院青海盐湖研究所,同年7月加入beat365官方网站从事教学科研工作,2013-2015年是德国弗莱堡大学访问学者。
主要研究方向为理论与计算有机化学、有机合成方法学、绿色化学,主持国家自然科学基金4项,在J. Am. Chem. Soc.、Angew. Chem. Int. Ed. 、Chem. Sci.等国际学术期刊发表SCI论文90余篇,申请国家发明专利20余项。论文被他引3400余次,多篇论文被评为热点论文、封面文章或高被引论文。
入选浙江省“万人计划”青年拔尖人才、温州市“高层次人才特殊支持计划”科技创新领军人才、温州市“551人才工程”,荣获温州市“尊重教育突出贡献教师”、温州大学“步青教学卓越奖”新秀奖、教学名师奖、温州大学“优秀教师”、林岛诺贝尔奖获得者大会“特邀青年学者”、中国科学院院长优秀奖等荣誉。
科研项目
1.国家自然科学基金: 过渡金属催化烯炔化合物环化反应机理的理论研究(21873074);
2.国家自然科学基金: 过渡金属催化含氧化导向基团的芳基碳氢活化反应机理研究(21572163);
3.国家自然科学基金:有机反应中炔基金属卡宾中间体反应活性的理论与实验研究(21372178);
4.浙江省自然科学基金:过渡金属催化邻炔基苯基衍生物环化反应的机理研究及新合成设计(LY13B020007);
5.国家自然科学基金:一系列镍催化的有机反应机理的理论研究(21002073)(已结题);
6.温州市科技计划:氟尿嘧啶氨基酸类化合物的计算机辅助设计合成及抗肿瘤活性(Y20100003)(已结题)。
代表性论文
2021年:
[90] Chen, J.; Joseph, D.; Xia, Y.; Lee, S.*, Amide/Ester Cross-Coupling via C-N/C-H Bond Cleavage: Synthesis of β-Ketoesters. The Journal of Organic Chemistry 2021,DOI: 10.1021/acs.joc.0c02868.
全文链接:https://doi.org/10.1021/acs.joc.0c02868
[89] Zhang, X.; Lin, B.; Chen, J.; Chen, J.; Luo, Y.; Xia, Y.*, Synthesis of Sulfimides and N-Allyl-N-(thio)amides by Ru(II)-Catalyzed Nitrene Transfer Reactions of N-Acyloxyamides. Organic Letters 2021, 23 (3), 819-825.
全文链接:https://doi.org/10.1021/acs.orglett.0c04043
[88] You, T.; Zhang, M.; Chen, J.*; Liu, H.; Xia, Y.*, Ruthenium(ii)-catalyzed reductive N–O bond cleavage of N-OR (R = H, alkyl, or acyl) substituted amides and sulfonamides. Organic Chemistry Frontiers 2021, 8 (1), 112-119.
全文链接:https://doi.org/10.1039/D0QO01093F
2020年:
[87] Chen, J.; Xia, Y.; Lee, S.*, Coupling of amides with ketones via C–N/C–H bond cleavage: a mild synthesis of 1,3-diketones. Organic Chemistry Frontiers 2020, 7 (19), 2931-2937.
全文链接:https://doi.org/10.1039/D0QO00797H
[86] Xia, S.; Jiang, Z.; Huang, Y.; Li, D.; Cui, Y.; Li, Y.*; Xia, Y.*, Synthesis of Titanium Complexes Supported by Carbinolamide- and Amide-Containing Ligands Derived from Ti(NMe2)4-Mediated Selective Amidations of Carbonyl Groups. Inorganic Chemistry 2020, 59 (19), 14031-14041.
全文链接:https://doi.org/10.1021/acs.inorgchem.0c01831
[85] Zhang, M.; Zhang, J.; Teng, Z.; Chen, J.; Xia, Y.*, Ruthenium(II)-Catalyzed Homocoupling of α-Carbonyl Sulfoxonium Ylides Under Mild Conditions: Methodology Development and Mechanistic DFT Study. Frontiers in Chemistry 2020, 8 (648).
全文链接:https://doi.org/10.3389/fchem.2020.00648
[84] Gao, K.; Xu, M.; Cai, C.; Ding, Y.; Chen, J.*; Liu, B.; Xia, Y.*, Cobalt-Catalyzed Reductive C–O Bond Cleavage of Lignin β-O-4 Ketone Models via In Situ Generation of the Cobalt–Boryl Species. Organic Letters 2020, 22 (15), 6055-6060.
全文链接:https://doi.org/10.1021/acs.orglett.0c02117
[83] Song, B.; Xie, P.; Li, Y.; Hao, J.; Wang, L.; Chen, X.; Xu, Z.; Quan, H.; Lou, L.; Xia, Y.*; Houk, K. N.*; Yang, W.*, Pd-Catalyzed Decarboxylative Olefination: Stereoselective Synthesis of Polysubstituted Butadienes and Macrocyclic P-glycoprotein Inhibitors. Journal of the American Chemical Society 2020, 142 (22), 9982-9992.
全文链接:https://doi.org/10.1021/jacs.0c00078
[82] Liu, H.; Cai, C.; Ding, Y.; Chen, J.*; Liu, B.; Xia, Y.*, Cobalt-Catalyzed E -Selective Isomerization of Alkenes with a Phosphine-Amido-Oxazoline Ligand. ACS Omega 2020, 5, 20, 11655–11670.
全文链接:https://dx.doi.org/10.1021/acsomega.0c00951
[81] Ghorai, S.; Lin, Y.; Xia, Y.*; Wink, D. J.; Lee, D.*, Silver-Catalyzed Selective Multicomponent Coupling Reactions of Arynes with Nitriles and Isonitriles. Organic Letters 2020, 22 (2), 642-647.
全文链接:https://doi.org/10.1021/acs.orglett.9b04416
[80] Chen, L.; Quan, H.; Xu, Z.; Wang, H.; Xia, Y.; Lou, L.*; Yang, W. *, A modular biomimetic strategy for the synthesis of macrolide P-glycoprotein inhibitors via Rh-catalyzed C-H activation. Nature Communications 2020, 11 (1), 2151.
全文链接:https://doi.org/10.1038/s41467-020-16084-0
[79] Chen, J.; Xia, Y.; Lee, S*, Transamidation for the Synthesis of Primary Amides at Room Temperature. Organic Letters 2020, 22 (9), 3504-3508.
全文链接:https://doi.org/10.1021/acs.orglett.0c00958
[78] Chen, J.-B.; Xu, M.; Zhang, J.-Q.; Sun, B.-B.; Hu, J.-M.; Yu, J.-Q.; Wang, X.-W.*; Xia, Y.*; Wang, Z.*, Modular Chiral Bisoxalamide–Copper-Catalyzed Asymmetric Oxo-Diels–Alder Reaction: Carbonyl Coordination for High Enantio- and Diastereocontrols. ACS Catalysis 2020, 10 (6), 3556-3563.
全文链接:https://doi.org/10.1021/acscatal.9b05606
[77] Chen, J.; Xu, M.; Yu, S.; Xia, Y.*; Lee, S.*, Nickel-Catalyzed Claisen Condensation Reaction between Two Different Amides. Organic Letters 2020, 22 (6), 2287-2292.
全文链接:https://doi.org/10.1021/acs.orglett.0c00485
[76] Liu, H.; Xu, M.; Cai, C.; Chen, J.*; Gu, Y.; Xia, Y.*, Cobalt-Catalyzed Z to E Isomerization of Alkenes: An Approach to (E)-β-Substituted Styrenes. Organic Letters 2020, 22 (3), 1193-1198.
全文链接:https://doi.org/10.1021/acs.orglett.0c00072
[75] Chen, F.-J.; Lin, Y.; Xu, M.; Xia, Y.*; Wink, D. J.; Lee, D.*, C–H Insertion by Alkylidene Carbenes To Form 1,2,3-Triazines and Anionic [3 + 2] Dipolar Cycloadditions To Form Tetrazoles: Crucial Roles of Stereoelectronic and Steric Effects. Organic Letters 2020, 22 (2), 718-723.
全文链接:https://doi.org/10.1021/acs.orglett.9b04548
[74] Ghorai, S.; Lin, Y.; Xia, Y.*; Wink, D. J.; Lee, D.*, Silver-Catalyzed Annulation of Arynes with Nitriles for Synthesis of Structurally Diverse Quinazolines. Organic Letters 2020, 22 (2), 626-630.
全文链接:https://doi.org/10.1021/acs.orglett.9b04395
2019年:
[73] Tong-De Tan, Xin-Qi Zhu, Mei Jia, Yongjia Lin, Jun Cheng*, Yuanzhi Xia*, Long-Wu Ye*, Stereospecific access to bridged [n.2.1] skeletons through gold-catalyzed tandem reaction of indolyl homopropargyl amides. Chinese Chemical Letters 2019, 31 (5).
全文链接:https://doi.org/10.1016/j.cclet.2019.10.019
[72] Yao, X.; Shao, Y.; Hu, M.; Xia, Y.; Cheng, T.; Chen, J.*, Palladium-Catalyzed Cascade Reaction of o-Cyanobiaryls with Arylboronic Acids: Synthesis of 5-Arylidene-7-aryl-5H-dibenzo[c,e]azepines. Organic Letters 2019, 21 (19), 7697-7701.
全文链接:https://doi.org/10.1021/acs.orglett.9b02351
[71] Yao, X.; Shao, Y.; Hu, M.; Zhang, M.; Li, S.; Xia, Y.; Cheng, T.; Chen, J.*, Palladium-Catalyzed Selective Synthesis of Dibenzo[c,e]azepin-5-ols and Benzo[c]pyrido[2,3-e]azepin-5-ols. Adv. Synth. Catal. 2019, 361 (20), 4707-4713.
全文链接:https://doi.org/10.1002/adsc.201900705
[70] Lin, B.; Kuang, J.; Chen, J.; Hua, Z.; Khakyzadeh, V.; Xia, Y.*, A one-pot protocol for the synthesis of β-ketosulfones from α,α-dibromoketones. Organic Chemistry Frontiers 2019, 6 (15), 2647-2653.
全文链接:https://doi.org/10.1039/C9QO00440H
[69] Han, S.; Kim, H.-S.; Zhang, M.; Xia, Y.*; Lee, S.*, Ni/Cu-Catalyzed Decarboxylative Addition of Alkynoic Acids to Terminal Alkynes for the Synthesis of gem-1,3-Enynes. Organic Letters 2019, 21 (14), 5426-5431.
全文链接:https://doi.org/10.1021/acs.orglett.9b01625
[68] Khakyzadeh, V.; Rostami, A.; Veisi, H.; Shirmardi Shaghasemi, B.; Reimhult, E.; Luque, R.; Xia, Y.; Darvishi, S.*, Direct C–S bond formation via C–O bond activation of phenols in a crossover Pd/Cu dual-metal catalysis system. Organic & Biomolecular Chemistry 2019, 17 (18), 4491-4497.
全文链接:https://doi.org/10.1039/C9OB00313D
[67] Lin, Y.; Zhou, T.; Guo, W.; Teng, Z.; Xia, Y.*, The mechanism of the gold-catalyzed intramolecular [3 + 2]-cycloaddition of 1,6-diynes: a DFT study. Dalton Transactions 2019, 48 (17), 5698-5704.
全文链接:https://doi.org/10.1039/C9DT00553F
[66] Kuang, J.; Zhou, T.; You, T.; Chen, J.; Su, C.; Xia, Y.*, Facile access to 1,3-diketones by gold(i)-catalyzed regioselective hydration of ynones. Organic & Biomolecular Chemistry 2019, 17 (16), 3940-3944.
全文链接:https://doi.org/10.1039/C9OB00494G
[65] Gupta, S.; Lin, Y.; Xia, Y.*; Wink, D. J.; Lee, D.*, Alder-ene reactions driven by high steric strain and bond angle distortion to form benzocyclobutenes. Chemical science 2019, 10 (7), 2212-2217.
全文链接:https://pubmed.ncbi.nlm.nih.gov/30931094/
[64] Jin, H.; Feng, X.; Li, J.; Li, M.; Xia, Y.; Yuan, Y.; Yang, C.; Dai, B.; Lin, Z.; Wang, J.; Lu, J.; Wang, S.*, Heteroatom-Doped Porous Carbon Materials with Unprecedented High Volumetric Capacitive Performance. Angew. Chem. Int. Ed. 2019, 58 (8), 2397-2401.
全文链接:https://doi.org/10.1002/anie.201813686
[63] Kuang, J.; Xia, Y.*; Yang, A.; Zhang, H.; Su, C.*; Lee, D., Copper-catalyzed aminothiolation of terminal alkynes with tunable regioselectivity. Chemical Communications 2019, 55 (12), 1813-1816.
全文链接:https://doi.org/10.1039/C8CC09122F
2018年:
[62] Liu, W.; Hu, Y.-Q.; Hong, X.-Y.; Li, G.-X.; Huang, X.-B.; Gao, W.-X.; Liu, M.-C.; Xia, Y.*; Zhou, Y.-B.*; Wu, H.-Y.*, Direct synthesis of 3-acylbenzothiophenes via the radical cyclization of 2-alkynylthioanisoles with α-oxocarboxylic acids. Chemical Communications 2018, 54 (100), 14148-14151.
全文链接:https://doi.org/10.1039/C8CC07735E
[61] Yu, S.; Shin, T.; Zhang, M.; Xia, Y.; Kim, H.; Lee, S.*, Nickel/Briphos-Catalyzed Direct Transamidation of Unactivated Secondary Amides Using Trimethylsilyl Chloride. Organic Letters 2018, 20 (23), 7563-7566.
全文链接:https://doi.org/10.1021/acs.orglett.8b03304
[60]. Pan, J.-L.; Xie, P.; Chen, C.; Hao, Y.; Liu, C.; Bai, H.-Y.; Ding, J.; Wang, L.-R.; Xia, Y.*; Zhang, S.-Y.*, Rhodium(III)-Catalyzed Redox-Neutral Cascade [3 + 2] Annulation of N-Phenoxyacetamides with Propiolates via C–H Functionalization/Isomerization/Lactonization. Organic Letters 2018, 20 (22), 7131-7136.
全文链接:https://doi.org/10.1021/acs.orglett.8b03082
[59] Xia, Y.; Lee, N.-K.; Sabbasani, V. R.; Gupta, S.; Lee, D.*, Reaction of silylallenes with triplet molecular oxygen. Organic Chemistry Frontiers 2018, 5 (17), 2542-2546.
全文链接:https://doi.org/10.1039/C8QO00390D
[58] Xie, P.; Guo, W.; Chen, D.; Xia, Y.*, Multiple pathways for C–H cleavage in cationic Cp*Rh(iii)-catalyzed C–H activation without carboxylate assistance: a computational study. Catalysis Science & Technology 2018, 8 (16), 4005-4009.
全文链接:https://doi.org/10.1039/C8CY00870A
[57] Gupta, S.; Xie, P.; Xia, Y.*; Lee, D.*, Reactivity of arynes toward functionalized alkenes: intermolecular Alder-ene vs. addition reactions. Organic Chemistry Frontiers 2018, 5 (14), 2208-2213.
全文链接:https://doi.org/10.1039/C8QO00470F
[56] Karmakar, R.; Le, A.; Xie, P.; Xia, Y.; Lee, D.*, Reactivity of Arynes for Arene Dearomatization. Organic Letters 2018, 20 (14), 4168-4172.
全文链接:https://doi.org/10.1021/acs.orglett.8b01466
[55] Jia, M.; Zhang, H.; Lin, Y.; Chen, D.; Chen, Y.; Xia, Y.*, Consecutive Lossen rearrangement/transamidation reaction of hydroxamic acids under catalyst- and additive-free conditions. Organic & Biomolecular Chemistry 2018, 16 (19), 3615-3624.
全文链接:https://doi.org/10.1039/C8OB00490K
[54] Peipei, X.; Jia, M.; Xu, X.-H.; Chen, F.; Xia, Y.*, Mechanistic DFT Study on Rhodium(III)-Catalyzed Double C-H Activation for Oxidative Annulations of 2-Substituted Imidazoles and Alkynes. Asian Journal of Organic Chemistry 2018, 7.
全文链接:https://doi.org/10.1002/ajoc.201700625
[53] Wang, Z.; Xie, P.; Xia, Y.*, Recent progress in Ru(II)-catalyzed C–H activations with oxidizing directing groups. Chinese Chemical Letters 2018, 29 (1), 47-53.
全文链接:https://doi.org/10.1016/j.cclet.2017.06.018
2017年:
[52] Gupta, S.; Xie, P.; Xia, Y.*; Lee, D.*, Reactivity and Selectivity in the Intermolecular Alder–Ene Reactions of Arynes with Functionalized Alkenes. Organic Letters 2017, 19 (19), 5162-5165.
全文链接:https://doi.org/10.1021/acs.orglett.7b02438
[51] Wang, X.; Xie, P.; Qiu, R.*; Zhu, L.; Liu, T.; Li, Y.; Iwasaki, T.; Au, C.-T.; Xu, X.; Xia, Y.*; Yin, S.-F.*; Kambe, N., Nickel-catalysed direct alkylation of thiophenes via double C(sp3)–H/C(sp2)–H bond cleavage: the importance of KH2PO4. Chemical Communications 2017, 53 (59), 8316-8319.
全文链接:https://doi.org/10.1039/C7CC04252C
[50] Sun, Q.; Xie, P.; Yuan, D.*; Xia, Y.*; Yao, Y., Regioselective addition of C(sp3)–H bonds of alkyl pyridines to olefins catalysed by cationic zirconium complexes. Chemical Communications 2017, 53 (53), 7401-7404.
全文链接:https://doi.org/10.1039/C7CC03263C
[49] Sabbasani, V. R.; Lee, H.; Xie, P.; Xia, Y.*; Lee, D.*, Cyclization of Ynamide-Tethered 1,3,8-Triynes. 2017, 23 (34), 8161-8165.
全文链接:https://doi.org/10.1002/chem.201701781
[48] Hu, K.; Qi, L.; Yu, S.; Cheng, T.; Wang, X.; Li, Z.; Xia, Y.; Chen, J.*; Wu, H., Efficient synthesis of isoquinolines in water by a Pd-catalyzed tandem reaction of functionalized alkylnitriles with arylboronic acids. Green Chemistry 2017, 19 (7), 1740-1750.
全文链接:https://doi.org/10.1039/C7GC00267J
[47] You, T.; Wang, Z.; Chen, J.; Xia, Y.*, Transfer Hydro-dehalogenation of Organic Halides Catalyzed by Ruthenium(II) Complex. The Journal of Organic Chemistry 2017, 82 (3), 1340-1346.
全文链接:https://doi.org/10.1021/acs.joc.6b02222
2016年及之前:
[46] Karmakar, R.; Mamidipalli, P.; Salzman, R. M.; Hong, S.; Yun, S. Y.; Guo, W.; Xia, Y.*; Lee, D.*, Benzannulation of Triynes Initiated by an Alder-Ene Reaction and Subsequent Trifluoromethylthiolate Addition. Organic Letters 2016, 18 (15), 3530-3533.
全文链接:https://doi.org/10.1021/acs.orglett.6b01443
[45] Chen, J.; Guo, W.; Wang, Z.; Hu, L.; Chen, F.*; Xia, Y.*, Unexpected Role of p-Toluenesulfonylmethyl Isocyanide as a Sulfonylating Agent in Reactions with α-Bromocarbonyl Compounds. The Journal of Organic Chemistry 2016, 81 (13), 5504-5512.
全文链接:https://doi.org/10.1021/acs.joc.6b00844
[44] Chen, J.; Guo, W.; Xia, Y.*, Computational Revisit to the β-Carbon Elimination Step in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and Cyclopropenes. The Journal of Organic Chemistry 2016, 81 (6), 2635-2638.
全文链接:https://doi.org/10.1021/acs.joc.6b00003
[43] Venkata R. Sabbasani, Hyunjin Lee, Yuanzhi Xia*, Daesung Lee*, Angew. Chem. Int. Ed. 2016, 55, 1151.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201510006/abstract
[42] Matthew J. O’Connor, Huaqing Liu , Daesung Lee*, Tao Zhou, Yuanzhi Xia*, Molecules 2015, 20, 21433.
全文链接:http://www.mdpi.com/1420-3049/20/12/19783
[41] Venkata R. Sabbasani, Genping Huang, Yuanzhi Xia*, Daesung Lee*, Chem. Eur. J. 2015, 21,17210.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201503243/abstract
[40] Pan Gao, Wei, Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia*, Zhuangzhi Shi*, J. Am. Chem. Soc. 2015, 137, 12231.
全文链接:http://pubs.acs.org/doi/abs/10.1021/jacs.5b06758
[39] Yanhua Mi, Tao Zhou, Kung-Pern Wang, Daesung Lee*, Yuanzhi Xia*, Chem. Eur. J. 2015, 21, 17256.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201502469/abstract
[38] R. Karmakar, S. Ghorai, Yuanzhi Xia, Daesung Lee*, Molecules 2015, 20, 15862.
全文链接:http://www.mdpi.com/1420-3049/20/9/15862
[37] Wei Guo, Yuanzhi Xia*, J. Org. Chem. 2015, 80, 8113.
全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.joc.5b01201
[36] Wei Guo, Tao Zhou, Yuanzhi Xia*, Organometallics, 2015, 34, 3012.
全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00317
[35] Tao Zhou, Wei Guo, Yuanzhi Xia*, Chem. Eur. J. 2015, 21, 9209.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201500558/abstract
[34] R. Karmakar, S. Y. Yun, Jiajia Chen, Yuanzhi Xia*, and Daesung Lee*, Angew. Chem. Int. Ed. 2015, 54, 6582.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201412468/abstract
[33] Genping Huang, Yuanzhi Xia*, ACS Catal. 2015, 5, 859.
全文链接:http://pubs.acs.org/doi/abs/10.1021/cs501738p
[32] Wei Guo, Yuanzhi Xia*, Synthesis 2014, 46, 2149.
全文链接:https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0034-1378281
[31] Ming-Bo Zhou, Rui Pi, Ming Hu, Yuan Yang, Ren-Jie Song, Yuanzhi Xia*, and Jin-Heng Li*, Angew. Chem. Int. Ed. 2014, 53, 11338.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201407175/abstract
[30] Yi Wang, Wei Liao, Genping Huang, Yuanzhi Xia, Zhi-Xiang Yu*, J. Org. Chem. 2014, 79, 5684.
全文链接:http://pubs.acs.org/doi/abs/10.1021/jo500839c
[29] Tao Zhou, Yuanzhi Xia*, Organometallics, 2014, 33, 4230.
全文链接:http://pubs.acs.org/doi/abs/10.1021/om500499s
[28] Nam-Kyu Lee, Sang Young Yun, Phani Mamidipalli, Ryan M. Salzman, Daesung Lee*, Tao Zhou, and Yuanzhi Xia*, J. Am. Chem. Soc. 2014, 136, 4363.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ja500292x
[27] Phani Mamidipalli, Sang Young Yun, Kung-Pern Wang, Tao Zhou, Yuanzhi Xia*, and Daesung Lee*, Chem. Sci. 2014, 5, 2362.
全文链接:http://pubs.rsc.org/en/Content/ArticleLanding/2014/SC/C3SC53478B
[26] Tao Zhou, Liang Xu, and Yuanzhi Xia*, Org. Lett. 2013, 15, 6074.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ol4029644
[25] Venkata R. Sabbasani, Phani Mamidipalli, Huijie Lu, Yuanzhi Xia, and Daesung Lee*, Org. Lett. 2013, 15, 1552.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ol400331r
[24] Genping Huang, Yuanzhi Xia*, Chunrui Sun, Jingwei Li, and Daesung Lee*, “Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates”. J. Org. Chem. 2013, 78, 988.
全文链接:http://pubs.acs.org/doi/abs/10.1021/jo302466z
[23] Chunrui Sun, Jingwei Li, Daesung Lee*, Genping Huang and Yuanzhi Xia*, “Formal C–H Amination of Cyclopropenes”. Chem. Commun. 2012, 48, 10990-10992.
全文链接:http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc35329f
[22] Ji-Cheng Wu, Lu-Bing Gong, Yuanzhi Xia, Ren-Jie Song, Ye-Xiang Xie, Jin-Heng Li* “Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones”. Angew. Chem. Int. Ed. 2012, 51, 9909.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201205969/abstract
[21] Bo-Xiao Tang, Yue-Hua Zhang, Ren-Jie Song, Dong-Jun Tang, Guo-Bo Deng, Zhi-Qiang Wang, Ye-Xiang Xie, Yuan-Zhi Xia, and Jin-Heng Li*, “Intramolecular ipso-Halocyclization of 4-(p-Unsubstituted-aryl)-1-alkynes Leading to Spiro[4,5]trienones: Scope, Application, and Mechanistic Investigations”. J. Org. Chem. 2012, 77, 2837.
全文链接:http://pubs.acs.org/doi/abs/10.1021/jo300037n
[20] Zhou Chen, Jian Wu, Yanmei Chen, Lei Li, Yuanzhi Xia*, Yahong Li*, Wei Liu, Tao Lei, Lijuan Yang, Dandan Gao, and Wu Li. “Rapid Accesses to Substituted Piperazines via Ti(NMe2)4-Mediated C-C Bond-Making Reactions”. Organometallics 2012, 31, 6005-6013.
全文链接:http://pubs.acs.org/doi/abs/10.1021/om300022u
[19] Genping Huang, Kelei Xie, Daesung Lee, Yuanzhi Xia*.“Reactivity of Alkynyl Metal-Carbenoids: DFT Study on the Pt-Catalyzed Cyclopropanation of Propargyl Ester-containing 1,3-Diynes”. Org. Lett. 2012, 14, 3850.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ol301497v
[18] Bing Cheng, Genping Huang, Liang Xu, Yuanzhi Xia*. “Mechanism of the N-Protecting Group Dependent Annulations of 3-Aryloxy Alkynyl Indoles under Gold Catalysis: A Computational Study”. Org. Biomol. Chem. 2012, 10, 4417.
全文链接:http://pubs.rsc.org/en/content/articlehtml/2012/ob/c2ob25316j
[17] Liang Xu, Qi Zhu, Genping Huang, Bing Cheng, Yuanzhi Xia*. “Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C-H Functionalization”. J. Org. Chem. 2012, 77, 3017. (Featured article, 封面文章).
全文链接:http://pubs.acs.org/doi/abs/10.1021/jo202431q
封面链接:http://pubs.acs.org/action/showLargeCover?issue=362713648
[16] Gengping Huang, Bing Cheng, Liang Xu, Yahong Li*, Yuanzhi Xia*. “Mechanism of the Transition Metal-Catalyzed Hydroarylation of Bromo-Alkyne Revisited: Hydrogen versus Bromine Migration”. Chem. Eur. J. 2012, 18, 5401.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201102692/abstract
[15] Yuanzhi Xia*, Genping Huang. “Mechanisms of the Au- and Pt-Catalyzed Intramolecular Acetylenic Schmidt Reactions: A DFT Study”.J. Org. Chem. 2010, 75, 7842.
全文链接:http://pubs.acs.org/doi/abs/10.1021/jo202431q
(以下为夏远志教授在研究生期间的主要成果,导师:余志祥教授和李亚红教授)
[14] Yuanzhi Xia, Alexander S. Dudnik, Yahong Li*, Vladimir Gevorgyan*. “On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines”. Org. Lett. 2010, 12, 5538-5541.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ol1024794
[13] Yuanzhi Xia, A. S. Dudnik, V. Gevorgyan, Yahong Li* “Mechanistic Insighs into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity”. J. Am. Chem. Soc. 2008, 130, 6940-6941.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ja802144t
[12] Yuanzhi Xia, Yong Liang, Yuanyuan Chen, Ming Wang, Lei Jiao, Feng Huang, Song Liu, Yahong Li, Zhi-Xiang Yu* “An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes”. J. Am. Chem. Soc. 2007, 129, 3470-3471.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ja068215h
[11] Yuanzhi Xia, Yahong Li*, Wu Li “Theoretical Study on the Consecutive 1,2-Hydroboration and 1,1-Organoboration Reactions of Alkyn-1-yl(vinyl)silanes with Borane”. J. Organomet. Chem. 2008, 693, 3722-3728.
全文链接:http://www.sciencedirect.com/science/article/pii/S0022328X08005524
[10] Yuanzhi Xia, Fengying Zhou, Yahong Li*, Wu Li. “Effect of Electron-withdrawing group on the [3,3]-Sigmatropic Rearrangements of 1,5-Enynes, 1,5-Diynes and 1,2-Diene-5-ynes: A Theoretical Study”.J. Mol. Struct. (THEOCHEM ) 2009, 904, 69-73.
全文链接:http://www.sciencedirect.com/science/article/pii/S0166128009001407
[9] Alexander S. Dudnik, Yuanzhi Xia, Yahong Li*, Vladimir Gevorgyan*.“Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans”. J. Am. Chem. Soc. 2010, 132, 7645-7655.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ja910290c
[8] Genping Huang, Yuanzhi Xia, Yahong Li. “Substituent Effects on the Tautomerism of Monochalcogenocarboxylic Acids XC(O)YH (X=H, F, NH2, OH, CN, and CH3; Y=S, Se, and Te): A Theoretical Study”. J. Mol. Struct. (THEOCHEM ) 2009, 896, 80-84.
全文链接:http://www.sciencedirect.com/science/article/pii/S0166128008006738
[7] Wei Ren, Yuanzhi Xia, Shun-Jun Ji, Yong Zhang, Xiaobing Wan*, Jing Zhao. “Wacker-Type Oxidation of Alkynes into 1,2-Diketones Using Molecular Oxygen”. Org. Lett. 2009, 11, 1841-1844.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ol900344g
[6] Yong Liang, Song Liu, Yuanzhi Xia, Yahong Li, Zhi-Xiang Yu*. “Mechanism, Regioselectivity, and the Kinetics of Phosphine-Catalyzed [3+2] Cycloaddition Reactions of Allenoates and Electron-deficient Alkenes”. Chem. Eur. J. 2008, 14, 4361-4373.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.200701725/abstract
[5] Xiaojuan Cheng, Yuanzhi Xia, Hua Wei, Bin Xu, Chongguang Zhang, Yahong Li*, Guimin Qian, Xiaohua Zhang, Kai Li, Wu Li. “Lewis Acid Catalyzed Intermolecular Olefin Hydroamination: Scope, Limitation, and Mechanism”. Eur. J. Org. Chem. 2008, 1929-1936.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200701080/abstract
[4] Jing-Wen Ran, Su-Yun Zhang, Bin Xu, Yuanzhi Xia, Dong Guo, Jing-Yan Zhang, Yahong Li*. “Tetranuclear Nickel(II) Complex with Tripodal Hydroxyl Ligand Functionalized by Additional Salicylaldehyde Donor Pendant: Synthesis, Crystal Structure and Magnetic Property”. Inorg. Chem. Commun. 2008, 11, 73-76.
全文链接:http://www.sciencedirect.com/science/article/pii/S1387700307003759
[3] Fu-Qiang Shi, Xin Li, Yuanzhi Xia, Liming Zhang, Zhi-Xiang Yu* “DFT Study of the Mechanisms of In Water Au(I)-Catalyzed Tandem [3,3]-Rearrangement/Nazarov Reaction/[1,2]-Hydrogen Shift of Enynyl Acetates: A Proton-Transport Catalysis Strategy in the Water-Catalyzed [1,2]-Hydrogen Shift” J. Am. Chem. Soc. 2007, 129, 15503-15512.
全文链接:http://pubs.acs.org/doi/abs/10.1021/ja071070%2B
[2] Hua Wei, Guimin Qian, Yuanzhi Xia, Kai Li, Yahong Li*, Wu Li. “BiCl3-Catalyzed Hydroamination of Norbornene with Aromatic Amines”. Eur. J. Org. Chem. 2007, 4471-4474.
全文链接:http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200700483/abstract
[1] Abraham F. Jalbout,* Bartosz Trzaskowski,* Yuanzhi Xia, Yahong Li. “Geometry Predictions, Vibrational Analysis and IR Intensities of XH3Y (X=C, Si, Ge, Y=F, Cl, Br) Calculated by Hybrid Density Functional Theory, MP2 and MP4 Methods” Acta Chim. Slov. 2007, 54, 769-777.
全文链接:http://acta.chem-soc.si/54/54-4-769.pdf
课题组网页:https://www.x-mol.com/groups/xia_yuanzhi